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Zirconium dioxide

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Zirconium dioxide
Archivo:ZrO2powder.jpg
IUPAC name Zirconium dioxide
Zirconium(IV) oxide
Other names Zirconia
Baddeleyite
Identifiers
CAS number 1314-23-4
Properties
Molecular formula ZrO2
Molar mass 123.218 g/mol
Appearance white powder
Density 5.68 g/cm3
Melting point

2715 °C

Boiling point

4300 °C

Solubility in water negligible
Solubility soluble in HF, and hot HSO4, HNO3, HCl
Refractive index (nD) 2.13
Thermochemistry
Std enthalpy of
formation
ΔfHo298
–1080 kJ/mol
Standard molar
entropy
So298
50.3 J K–1 mol–1
Hazards
MSDS MSDS
EU Index Not listed
Flash point Non-flammable
LD50 > 8.8 g/kg (oral, rat)
Related compounds
Other anions Zirconium disulfide
Other cations Titanium dioxide
Hafnium dioxide
 Yes checkY (what is this?)  (verify)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Zirconium dioxide (ZrO2), sometimes known as zirconia (not to be confused with zircon), is a white crystalline oxide of zirconium. Its most naturally occurring form, with a monoclinic crystalline structure, is the rare mineral, baddeleyite. The high temperature cubic crystalline form, called 'cubic zirconia', is rarely found in nature as mineral tazheranite (Zr,Ti,Ca)O2 (and a doubtful mineral arkelite), but is synthesized in various colours for use as a gemstone. The cubic crystal structured variety cubic zirconia is the best-known diamond simulant.

Engineering propertiesEditar sección

Zirconium dioxide is one of the most studied ceramic materials. Pure ZrO2 has a monoclinic crystal structure at room temperature and transitions to tetragonal and cubic at increasing temperatures. The volume expansion caused by the cubic to tetragonal to monoclinic transformation induces very large stresses, and will cause pure ZrO2 to crack upon cooling from high temperatures. Several different oxides are added to zirconia to stabilize the tetragonal and/or cubic phases: magnesium oxide (MgO), yttrium oxide, (Y2O3), calcium oxide (CaO), and cerium(III) oxide (Ce2O3), amongst others.[1]

Zirconia is very useful in its 'stabilized' state. In some cases, the tetragonal phase can be metastable. If sufficient quantities of the metastable tetragonal phase is present, then an applied stress, magnified by the stress concentration at a crack tip, can cause the tetragonal phase to convert to monoclinic, with the associated volume expansion. This phase transformation can then put the crack into compression, retarding its growth, and enhancing the fracture toughness. This mechanism is known as transformation toughening, and significantly extends the reliability and lifetime of products made with stabilized zirconia. [1][2]

A special case of zirconia is that of tetragonal zirconia polycrystaline or TZP, which is indicative of polycrystalline zirconia composed of only the metastable tetragonal phase.

The cubic phase of zirconia also has a very low thermal conductivity, which has led to its use as a thermal barrier coating or TBC in jet and diesel engines to allow operation at higher temperatures. Thermodynamically the higher the operation temperature of an engine, the greater the possible efficiency (see Carnot heat engine). As of 2004, a great deal of research is ongoing to improve the quality and durability of these coatings. It is used as a refractory material, in insulation, abrasives, enamels and ceramic glazes. Stabilized zirconia is used in oxygen sensors and fuel cell membranes because it has the ability to allow oxygen ions to move freely through the crystal structure at high temperatures. This high ionic conductivity (and a low electronic conductivity) makes it one of the most useful electroceramics.

The ZrO2 band gap is dependent on the phase (cubic, tetragonal, monoclinic, or amorphous) and preparation methods, with typical estimates from 5-7 eV.[3]

This material is also used in the manufacture of subframes for the construction of dental restorations such as crowns and bridges, which are then veneered with a conventional feldspathic porcelain.[4]

Zirconium dioxide can occur as a white powder which possesses both acidic and basic properties. On account of its infusibility and brilliant luminosity when incandescent, it was used as an ingredient of sticks for limelight.

Zirconia is also an important high-k dielectric material that is being investigated for potential applications as an insulator in transistors in future nanoelectronic devices.

Diamond simulantEditar sección

Main gallery: Cubic zirconia.
Archivo:CZ brilliant.jpg

Single crystals of the cubic phase of zirconia are commonly used as diamond simulant in jewelery. Like diamond, cubic zirconia has a cubic crystal structure and a high index of refraction. Discerning a good quality cubic zirconia gem from a diamond is difficult, and most jewellers will have a thermal conductivity tester to identify cubic zircona by its low thermal conductivity (diamond is a very good thermal conductor). This state of zirconia is commonly called "cubic zirconia," "CZ," or "zircon" by jewellers, but the last name is not chemically accurate. Zircon is actually the mineral name for naturally occurring zirconium silicate (ZrSiO4). Its transparent form is also used as a gemstone, and its opaque form as a refractory.

PatentsEditar sección

On August 7, 2006, Apple Inc. filed a patent for using zirconia oxide ceramics as casing for mobile devices. Some of the current iPods contain radios for built-in Nike+, Bluetooth, or wireless networking. Using zirconia-based ceramics rather than steel or aluminium for its radio transparency characteristics would enable such internal antennae to be within the device, without the need for changes in thickness or a window, like the iPod touch.[5]

See alsoEditar sección

ReferencesEditar sección

  1. 1,0 1,1 Evans, A.G., Cannon, R.M. (1986). "Toughening of brittle solids by martensitic transformations". Acta Met. 34: 761. doi:10.1016/0001-6160(86)90052-0. 
  2. Porter, D.L., Evans, A.G., Heuer, A.H. (1979). "Transformation toughening in PSZ". Acta Met. 27: 1649. doi:10.1016/0001-6160(79)90046-4. 
  3. Chang, Jane P; You-Sheng Lin; Karen Chu (2001). "Rapid thermal chemical vapor deposition of zirconium oxide for metal-oxide-semiconductor field effect transistor application". Journal of Vacuum Science & Technology B: 19 (5…): 1782–1787. doi:10.1116/1.1396639. 
  4. Papaspyridakos, Panos; Kunal Lal (2008). "Complete arch implant rehabilitation using subtractive rapid prototyping and porcelain fused to zirconia prosthesis: A clinical report". The Journal of Prosthetic Dentistry 100 (3): 165–172. doi:10.1016/S0022-3913(08)00110-8. 
  5. "Apple seeks patent on radio-transparent zirconia CE casings", Apple Insider, 30 November 2006.

Further readingEditar sección

  • Green, D.J.; Hannink, R.; Swain, M.V. (1989). Transformation Toughening of Ceramics. Boca Raton: CRC Press. ISBN 0-8493-6594-5. 
  • Heuer, A.H., Hobbs, L.W., Eds., Science and Technology of Zirconia, Adv. Ceram., Vol. 3, p. 475 (ACerS, Columbus, OH 1981)
  • Claussen, N., Rühle, M., Heuer, A.H., Proc. 2nd Int'l Conf. on Science and Technology of Zirconia, Adv. Ceram., Vol. 11 (ACerS, Columbus, OH 1984)

External linksEditar sección



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